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61.
Eckfeld Maar: Window into an Eocene Terrestrial Habitat in Central Europe   总被引:1,自引:1,他引:0  
<正>To mark the occasion of the 175th anniversary of the Rheinische Naturforschende Gesellschaft in 2009 and of the centennial of the Mainz Natural History Museum in 2010,we present a short account of our present knowledge of the Eckfeld Maar after 20 years of continuous research.This paper does not attempt to include all of the detailed results on the geology of the Eckfeld site or its biota.To date,nearly 250 papers and books have been published since the start of our project.An up-to-date list of these publications can be found at www.eckfeldermaar. de.  相似文献   
62.
We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ11 B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ11 B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.  相似文献   
63.
The intra- and epicontinental basins in north-east Africa (Egypt, Sudan) bear ample evidence of weathering processes repeatedly having contributed to the formation of mineral deposits throughout the Phanerozoic.The relict primary weathering mantle of Pan-African basement rocks consists of kaolinitic saprolite, laterite (in places bauxitic) and iron oxide crust. On the continent, the reaccumulation of eroded weathering-derived clay minerals (mainly kaolinite) occurred predominantly in fluvio-lacustrine environments, and floodplain and coastal plain deposits. Iron oxides, delivered from ferricretes, accumulated as oolitic ironstones in continental and marine sediments. Elements leached from weathering profiles accumulated in continental basins forming silcrete and alunite or in the marine environment contributing to the formation of attapulgite/saprolite and phosphorites.The Early Paleozoic Tawiga bauxitic laterite of northern Sudan gives a unique testimony of high latitude lateritic weathering under global greenhouse conditions. It formed in close spatial and temporal vicinity to the Late Ordovician glaciation in north Africa. The record of weathering products is essentially complete for the Late Cretaceous/Early Tertiary. From the continental sources in the south to the marine sinks in the north, an almost complete line of lateritic and laterite-derived deposits of bauxitic kaolin, kaolin, iron oxides and phosphates is well documented.  相似文献   
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We present data for the concentrations of eleven rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er, Yb, Lu) in eleven international geochemical reference materials obtained by isotope dilution multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We have analysed both rock powders and synthetic silicate glasses, and the latter provide precise data to support the use of these as reference materials for in situ trace element determination techniques. Our data also provide precise measurements of the abundance of mono-isotopic Pr in both glasses and powders, which allows more accurate constraints on the anomalous redox-related behaviour of Ce during geochemical processes. All materials were analysed in replicate providing data that typically reproduce to better than one percent. Sm/Nd ratios in all these materials also reproduce to better than 0.2% and are accurate to < 0.2% and can thus be used as calibrants for Sm-Nd geochronology. Our analyses agree well with existing data on these reference materials. In particular, for NIST SRM 610, USGS BHVO-2, AGV-1 and AGV-2, our measured REE abundances are typically within < 2% (and mostly 1%) of REE concentrations previously determined by isotope dilution analysis and thermal ionisation mass spectrometry, consistent with the higher degree of precision and accuracy obtained from isotope dilution techniques. Close agreement of results between basaltic glass reference materials USGS BHVO-2G and BCR-2G and the BHVO-2 and BCR-2 powders from which they were created suggests that little fractionation, concentration or dilution of REE contents occurred during glass manufacture.  相似文献   
67.
The gold mineralization of the Hutti Mine is hosted by nine parallel, N–S trending, steeply dipping, 2–10 m wide shear zones, that transect Archaean amphibolites. The shear zones were formed after peak metamorphism during retrograde ductile D2 shearing in the lower amphibolite facies. They were reactivated in the lower to mid greenschist facies by brittle–ductile D3 shearing and intense quartz veining. The development of a S2–S3 crenulation cleavage facilitates the discrimination between the two deformation events and contemporaneous alteration and gold mineralization. Ductile D2 shearing is associated with a pervasively developed distal chlorite–sericite alteration assemblage in the outer parts of the shear zones and the proximal biotite–plagioclase alteration in the center of the shear zones. D3 is characterized by development of the inner chlorite-K-feldspar alteration, which forms a centimeter-scale alteration halo surrounding the laminated quartz veins and replaces earlier biotite along S3. The average size of the laminated vein systems is 30–50 m along strike as well as down-dip and 2–6 m in width.Mass balance calculations suggest strong metasomatic changes for the proximal biotite–plagioclase alteration yielding mass and volume increase of ca. 16% and 12%, respectively. The calculated mass and volume changes of the distal chlorite–sericite alteration (ca. 11%, ca. 8%) are lower. The decrease in δ18O values of the whole rock from around 7.5‰ for the host rocks to 6–7‰ for the distal chlorite–sericite and the proximal biotite–plagioclase alteration and around 5‰ for the inner chlorite-K-feldspar alteration suggests hydrothermal alteration during two-stage deformation and fluid flow.The ductile D2 deformation in the lower amphibolite facies has provided grain scale porosities by microfracturing. The pervasive, steady-state fluid flow resulted in a disseminated style of gold–sulfide mineralization and a penetrative alteration of the host rocks. Alternating ductile and brittle D3 deformation during lower to mid greenschist facies conditions followed the fault-valve process. Ductile creep in the shear zones resulted in a low permeability environment leading to fluid pressure build-up. Strongly episodic fluid advection and mass transfer was controlled by repeated seismic fracturing during the formation of laminated quartz(-gold) veins. The limitation of quartz veins to the extent of earlier shear zones indicate the importance of pre-existing anisotropies for fault-valve action and economic gold mineralization.  相似文献   
68.
Georeferencing is one of the most important tasks in photogrammetry. Traditionally it has been achieved indirectly using the well-known method of aerial triangulation. With the availability of integrated GPS and inertial measurement units (IMU), this situation changed. Direct determination of exterior orientation is now possible. Today, direct and integrated sensor orientation is used for a wide range of sensors including lidar and SAR, as well as for digital line scanner systems and aerial cameras. This paper investigates the performance of direct and integrated sensor orientation for large scale mapping using the data-set of the 'Integrated Sensor Orientation' test of the European Organisation for Experimental Photogrammetric Research (OEEPE—now known as EuroSDR). The concept, potential, problems and solutions of direct and integrated sensor orientation are discussed.  相似文献   
69.
Piecewise 1D laterally constrained inversion of resistivity data   总被引:1,自引:0,他引:1  
In a sedimentary environment, layered models are often capable of representing the actual geology more accurately than smooth minimum structure models. Furthermore, interval thicknesses and resistivities are often the parameters to which non‐geophysicist experts can relate and base decisions on when using them in waste site remediation, groundwater modelling and physical planning. We present a laterally constrained inversion scheme for continuous resistivity data based on a layered earth model (1D). All 1D data sets and models are inverted as one system, producing layered sections with lateral smooth transitions. The models are regularized through laterally equal constraints that tie interface depths and resistivities of adjacent layers. Prior information, e.g. originating from electric logs, migrates through the lateral constraints to the adjacent models, making resolution of equivalences possible to some extent. Information from areas with well‐resolved parameters will migrate through the constraints in a similar way to help resolve the poorly constrained parameters. The estimated model is complemented by a full sensitivity analysis of the model parameters, supporting quantitative evaluation of the inversion result. Examples from synthetic 2D models show that the model recognition of a sublayered 2D wedge model is improved using the laterally constrained inversion approach when compared with a section of combined 1D models and when compared with a 2D minimum structure inversion. Case histories with data from two different continuous DC systems support the conclusions drawn from the synthetic example.  相似文献   
70.
By performing buoyancy-driven fracture experiments in brittle gelatin we observe that the ascent velocity of a fracture containing a finite volume of fluid increases when approaching the free surface. We theoretically describe this free-surface effect and quantify it by introducing an effective depth-dependent fracture toughness and developing an ascent model on the basis of linear fracture mechanics. We develop a successful inversion approach and resolve the actual and critical fracture length and the ascent velocity far away from the free surface from the observation of the fracture tip migration alone. Other parameters, as the fluid volume included in the fracture and the in situ fracture toughness, can be derived. Applying the model and inversion to the 1998 eruption at Piton de la Fournaise, Reunion Island, reveals estimates of the length and critical length of the feeding magma batch, the magma batch volume and the in situ fracture toughness. It further indicates that the ascent velocity of the magma batch was probably much smaller at greater depths and that the batch might have been initiated several months or years before the eruption.  相似文献   
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